Tuesday, January 20, 2015

Insights into the effects of surface properties of oxides on the catalytic activity of Pd for C-C coupling reactions




Nanoscale , 2015, Advance Article

DOI: 10.1039/C4NR06482H, Paper

Sai Zhang, Jing Li, Wei Gao, Yongquan Qu

It has been experimentally found that ceria supports with strong basicity and high concentration of O-vacancies significantly enrich the electron density of Pd catalysts and accelerate the step of oxidative addition for C-C coupling reaction. The FTIR and XPS provide strong evidence supporting for this interfacial effect.

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