Tuesday, February 10, 2015

Self-assembly of an unprecedented polyoxomolybdate anion [Mo20O66]12- in a giant peanut-like 62-core silver-thiolate nanocluster

Nanoscale , 2015, Accepted Manuscript

DOI: 10.1039/C5NR00171D, Communication

Shuang-Quan Zang, Ren-Wu Huang, Qing-Qing Xu, Guang-Gang Gao, Hong-Lin Lu, Xiaokang Guo, Mingsheng Tang, Thomas C. W. Mak

A polyoxometalate-templated silver thiolate nanocluster, [Ag62(StBu)40(Mo20O66)(Mo6O19)3(CH3CN)2](CF3SO3)4 (1), has been isolated, in which a giant peanut-like silver(I)-thiolate cluster [Ag62(StBu)40]22+ encapsulates an unprecedented [Mo20O66]12- polyoxoanion core. It opens a new approach to...

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