Monday, October 05, 2015

Mechanistic Interpretation of Selective Catalytic Hydrogenation and Isomerization of Alkenes and Dienes by Ligand Deactivated Pd Nanoparticles

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR05090A, Paper
Jie Sheng Zhu, Young-Seok Shon
Unsupported thiolate-capped palladium nanoparticle catalysts are found to be highly substrate-selective for alkene hydrogenation and isomerization. Steric and poisoning effects from thiolate ligands on the nanoparticle surface control reactivity and...
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