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Friday, May 03, 2013

Preparation of high-quality biocompatible carbon dots by extraction, with new thoughts on the luminescence mechanisms

Rui Zhang, Yingbo Liu, Libo Yu, Zhen Li and Shuqing Sun



Recently, carbon dots (CDs) have been among the most promising emerging fluorescent labels for cellular imaging. In this work, a new facile synthesis method was developed for fabricating CDs from polystyrene foam waste and common organic solvents. The CDs obtained have tunable emission from blue to orange and are expected to be of use for labeling different cellular structures simultaneously. Transmission electron microscopy, x-ray diffraction, Raman spectra, Fourier transform infrared spectrometry, UV–vis, and fluorescence spectrophotometry (PL) were employed to investigate the structures and luminescence properties of CDs. The highest quantum yield (QY) achieved was 36%. The mechanisms for the formation and luminescence of the CDs are analyzed. The ability of the solvent to disperse the CDs plays a very important role in the origin of PL. The type of organic solvent has an important influence on the position of emission peaks and the QY. Different emissive traps play the domina...



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