Monday, June 09, 2014

Solvation chemistry of water-soluble thiol-protected gold nanocluster Au102 from DOSY NMR spectroscopy and DFT calculations




Nanoscale , 2014, Advance Article

DOI: 10.1039/C4NR01255K, Communication

Kirsi Salorinne, Tanja Lahtinen, Sami Malola, Jaakko Koivisto, Hannu Hakkinen

The hydrodynamic diameter of Aum (pMBA)n clusters in aqueous media was determined by DOSY NMR spectroscopy. The apparent size of the cluster was shown to depend on the counter ion of the deprotonated pMBA- ligand.

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