Monday, November 02, 2015

A three-dimensional interconnected hierarchical FeOOH/TiO2/ZnO nanostructural photoanode for enhancing the performance of photoelectrochemical water oxidation

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR06212H, Paper
Zhenhu Li, Shuanglong Feng, Shuangyi Liu, Xin Li, Liang Wang, Wenqiang Lu
A novel 3D interconnected ZnO/TiO2/FeOOH photoanode exhibits a largely enhanced photoelectrochemical performance via a cheap and low temperature chemical bath deposition process.
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Green microwave switching from oxygen rich yellow anatase to oxygen vacancy rich black anatase TiO2 solar photocatalyst using Mn(II) as 'anatase phase purifier'

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05975E, Paper
Sanjay Gopal Ullattil, Pradeepan Periyat
Green and rapid microwave synthesis of 'yellow oxygen rich' and 'black oxygen vacancy rich' anatase TiO2 solar photocatalysts.
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Electrically-charged recyclable graphene flakes entangled with electrospun nanofibers for the adsorption of organics for water purification

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05005G, Paper
Seongpil An, Hong Seok Jo, Kyo Yong Song, Mukund G. Mali, Salem S. Al-Deyab, Sam S. Yoon
Graphene flakes were entrapped between nylon 6 nanofiber layers and the resulting assembly was used as a recyclable water purification membrane.
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Electrically-charged recyclable graphene flakes entangled with electrospun nanofibers for the adsorption of organics for water purification

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05005G, Paper
Seongpil An, Hong Seok Jo, Kyo Yong Song, Mukund G. Mali, Salem S. Al-Deyab, Sam S. Yoon
Graphene flakes were entrapped between nylon 6 nanofiber layers and the resulting assembly was used as a recyclable water purification membrane.
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Multicatalytic colloids with highly scalable, adjustable, and stable functionalities in organic and aqueous media

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR06390F, Paper
Donghee Kim, Sanghyuk Cheong, Yun Gyong Ahn, Sook Won Ryu, Jai-Kyeong Kim, Jinhan Cho
Recyclable multicatalysts with high catalytic performance in aqueous and organic media are prepared using a layer-by-layer assembly of hydrophobic catalytic nanoparticles that can allow a single colloid to induce various catalytic reactions.
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Self-assembly of cationic multidomain peptide hydrogels: supramolecular nanostructure and rheological properties dictate antimicrobial activity

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05233E, Paper
Linhai Jiang, Dawei Xu, Timothy J. Sellati, He Dong
In this work, we will design and fabricate self-assembling peptide hydrogels with tunable supramolecular nanostructure and rheological properties and investigate the synergistic effect of supramolecular surface chemistry and the storage moduli on the antimicrobial activity of bulk hydrogels.
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Quantum spin hall insulators in strain-modified arsenene

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05006E, Paper
Haijun Zhang, Yandong Ma, Zhongfang Chen
DFT computations predicted that the suitable strain modulation of honeycomb arsenene results in a unique two-dimensional topological insulator with a sizable bulk gap, which could be characterized and utilized at room temperature.
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Interface formation of two- and three-dimensionally bonded materials in the case of GeTe-Sb2Te3 superlattices

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR04530D, Paper
Jamo Momand, Ruining Wang, Jos E. Boschker, Marcel A. Verheijen, Raffaella Calarco, Bart J. Kooi
The ground state crystal structure of GeTe-Sb2Te3 superlattices is actually a van der Waals heterostructure of Sb2Te3 and rhombohedral GeSbTe.
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Facile preparation and multifunctional applications of boron nitride quantum dots

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05960G, Communication
Zhouyue Lei, Shengjie Xu, Jiaxun Wan, Peiyi Wu
Boron nitride quantum dots are obtained by a facile sonication-solvothermal technique, proven to be promising fluorescence probes for bioimaging and also easily integrated into high-performance proton exchange membranes.
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Defective ZnFe2O4 nanorods with oxygen vacancy for photoelectrochemical water splitting

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05812K, Paper
Ju Hun Kim, Youn Jeong Jang, Jin Hyun Kim, Ji-Wook Jang, Sun Hee Choi, Jae Sung Lee
A 1D ZnFe2O4 photoanode is treated under a hydrogen or vacuum atmosphere to improve the photoelectrochemical water oxidation activity up to 20 times. This post-treatment creates oxygen vacancies in the ZnFe2O4 lattice that serve as a source of electron donors and passivates surface trap sites, and as a result improves charge transfer.
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Surface plasmon effect of carbon nanodots

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05918F, Communication
Deng-Yang Guo, Chong-Xin Shan, Kai-Kai Liu, Qing Lou, De-Zhen Shen
Carbon nanodots have been prepared, and they can be employed to enhance the fluorescence of ZnO quantum dots, and the enhancement can be attributed to the surface plasmon effect of the nanodots.
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Boron based two-dimensional crystals: theoretical design, realization proposal and applications

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR04359J, Review Article
Xian-Bin Li, Sheng-Yi Xie, Hui Zheng, Wei Quan Tian, Hong-Bo Sun
In this review, we summarize the recent developments of 2D boron based crystals. The theoretical design, possible experimental realization strategies and their potential technical applications are presented and discussed.
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Shape-controlled gold nanoparticles supported on MoS2 nanosheets: synergistic effect of thionine and MoS2 and their application for electrochemical label-free immunosensing

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05614D, Paper
Shao Su, Min Zou, He Zhao, Chengfeng Yuan, Yanan Xu, Chi Zhang, Lihua Wang, Chunhai Fan, Lianhui Wang
A label-free electrochemical immunosensor was developed based on clover-shaped AuNP-Thi-MoS2 nanocomposites.
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Spatial control of chromosomal location in a live cell with functionalized magnetic particles

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR04905A, Paper
Juhee Hong, Prashant Purwar, Misun Cha, Junghoon Lee
We demonstrated the movement of whole chromosomes over long distances by using bacterial magnetic particles conjugated to histone H1 antibodies (H1-BMPs), which specifically target and bind histone H1 on chromosomes.
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Cascade synthesis of a gold nanoparticle-network polymer composite

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR06594A, Paper
Simonida Grubjesic, Bryan S. Ringstrand, Katherine L. Jungjohann, Scott M. Brombosz, Sonke Seifert, Millicent A. Firestone
The multi-step, cascade synthesis of a self-supporting, hierarchically-structured gold nanoparticle hydrogel composite is described.
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Rectification of nanopores in aprotic solvents - transport properties of nanopores with surface dipoles

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR06340J, Paper
Timothy Plett, Wenqing Shi, Yuhan Zeng, William Mann, Ivan Vlassiouk, Lane A. Baker, Zuzanna S. Siwy
Surface dipoles rendered by adsorbed solvent molecules influence ionic transport at nanoscale.
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Biointerfacing polymeric microcapsules for in vivo near-infrared light-triggered drug release

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR06350G, Paper
Jingxin Shao, Mingjun Xuan, Tieyan Si, Luru Dai, Qiang He
Biointerfacing microcapsules combined with lipid bilayers and gold nanorods as a NIR-light-triggered drug release system were used for anticancer therapy in vivo.
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Resistive graphene humidity sensors with rapid and direct electrical readout

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR06038A, Paper
Open Access Open Access
Anderson D. Smith, Karim Elgammal, Frank Niklaus, Anna Delin, Andreas C. Fischer, Sam Vaziri, Fredrik Forsberg, Mikael Rasander, Hakan Hugosson, Lars Bergqvist, Stephan Schroder, Satender Kataria, Mikael Ostling, Max C. Lemme
We demonstrate resistive humidity sensing using a single-layer graphene patch placed on top of a SiO2 layer on a Si wafer.
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Controllable assembly of well-defined monodisperse Au nanoparticles on hierarchical ZnO microspheres for enhanced visible-light-driven photocatalytic and antibacterial activity

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR06359K, Paper
Yuan Wang, Hua-Bin Fang, Yan-Zhen Zheng, Rongqin Ye, Xia Tao, Jian-Feng Chen
An excellent visible-light-driven photocatalyst composed of well-defined monodisperse Au nanoparticles on ZnO microspheres via a layer-by-layer self-assembly technique is demonstrated.
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Novel self-assembled sandwich nanomedicine for NIR-responsive release of NO

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06630A, Paper
Qianjun He, Jing Fan, Yi Liu, Ying Ma, Xiao Fu, Yijing Liu, Peng Huang, Nongyue He, Xiaoyuan Shawn Chen
A novel sandwich nanomedicine (GO-BNN6) for near-infrared (NIR) light responsive release of nitric oxide (NO) has been constructed by self-assembling of graphene oxide (GO) nanosheets and a NO donor BNN6...
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The favorite of large misorientation angle grain boundaries in graphene

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR04960A, Paper
Feng Ding, Zhang Xiuyun, Ziwei Xu, Qinghong Yuan, John Xin
A grain boundary (GB) in graphene is a linear defect between two specifically oriented graphene edges, which title angles are denoted as [small theta]1, [small theta]2, respectively. Here we present a systematic...
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Real-Time Label-Free Quantitative Fluorescence Microscopy-Based Detection of ATP Using a Tunable Fluorescent Nano-Aptasensor Platform

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR05839B, Paper
Sajal Shrivastava, Il Yung Sohn, Young Min Son, Won-Il Lee, Nae_Eung Lee
Although real-time label-free fluorescent aptasensors based on nanomaterials are increasingly recognized as a useful strategy for the detection of target biomolecules with high fidelity, the lack of an imaging-based quantitative...
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Tuning plasmonic and chemical enhancement for SERS detection on graphene-based Au hybrids

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06010A, Paper
Xiu Liang, Benliang Liang, Zhenghui Pan, Xiu-feng Lang, Yuegang Zhang, Guang-Sheng Wang, peng-gang yin, Lin Guo
Various graphene-based Au nanocomposites have been developed as surface-enhanced Raman scattering (SERS) substrates recently. However, efficient use of SERS has been impeded by the difficulty of tuning SERS enhancement effects...
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Hydrogen Storage in Chemical Bond Stabilized Co9S8-Graphene Layered Structure

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06116D, Paper
Wei Qin, Lu Han, Hai Bi, Jiahuang Jian, Xiaohong Wu, Peng Gao
With the high energy ball milling method, Co9S8-decorated graphene (GE) composite, which shows excellent hydrogen storage capacity, has been successfully fabricated with well-organized layered structure. Moreover, the stabilized mechanism of...
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Surface bioengineering of diatomite based nanovectors for efficient intracellular uptake and drug delivery

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR05173H, Paper
Monica Terracciano, Mohammad-Ali Shahbazi, Alexandra Correia, Ilaria Rea, Annalisa Lamberti, Luca De Stefano, Helder A Santos
Diatomite is a natural porous silica material of sedimentary origin. Due to its peculiar properties, it can be considered as a valid surrogate of synthetic porous silica for nano-based drug...
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All-solution processed transparent organic light emitting diodes

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR05820A, Paper
Min Zhang, Stefan Hofle, Jens Czolk, Adrian Mertens, Alexander Colsmann
In this work, we report on indium tin oxide-free, all-solution processed transparent organic light emitting diodes (OLEDs) with an advanced inverted device architecture. Conductive polymer layers are employed as both...
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Plasmonic Fluorescent CdSe/Cu2S Hybrid Nanocrystals for Multichannel Imaging and Cancer Directed Photo-Thermal Therapy

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR05225D, Paper
Sheikh Mohamed, Aby Cheruvathoor Poulose, Srivani Veeranarayanan, Rebeca Romero Abeurto, Trevor Mitcham, Yuko Suzuki, Yasushi Sakamoto, Pulickel M. Ajayan, Richard R Bouchard, Yasuhiko Yoshida, Toru Maekawa, Sakthi Kumar D
A simple, crude Jatropha curcas (JC) oil-based synthesis approach, devoid of any toxic phosphine and pyrophoric ligands, to produce size and shape tuned CdSe QDs and a further copper sulfide...
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Fluorescence Enhancement on Silver Nanoplate at the Single- and Sub-Nanoparticle Level

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06146F, Paper
Yangbin Shen, Ting He, Wenhui Wang, Yulu Zhan, Xin Hu, Binfang Yuan, Xiaochun Zhou
The fluorescence intensity of fluorescent molecule could be strongly enhanced when the molecule is near a metal nanoparticle. Hence, fluorescence enhancement has a lot of applications in the fields of...
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Electrocatalysis Induced Elasticity Modulation in a Superionic Proton Conductor Probed by Band-Excitation Atomic Force Microscopy

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR04809E, Paper
Alexander B Papandrew, Qian Li, Mahmut Baris Okatan, S. Jesse, Chris Hartnett, Sergei V. Kalinin, Rama Krishnan Vasudevan
Variable temperature band-excitation atomic force microscopy in conjunction with I-V spectroscopy was used to investigate the crystalline superionic proton conductor CsHSO4 during proton exchange induced by a Pt-coated conductive scanning...
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Layered nano-gratings by electron beam writing to form 3-level diffractive optical elements for 3D phase-offset holographic lithography

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06822C, Communication
Liang Yuan, Peter Herman
Multilevel nanophotonic structure is a major goal in providing advanced optical functionalities such as found in photonics crystals and metamaterials. A three-level nano-grating phase mask has been fabricated in electron-beam...
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