Enhanced performance of polymer solar cell with ZnO nanoparticle electron transporting layer passivated by in situ cross-linked three-dimensional polymer network

An in situ cross-linked three-dimensional polymer network has been developed to passivate ZnO nanoparticles as an electron transporting layer (ETL) to improve the performance of inverted organic solar cells. The passivated ZnO ETL-based devices achieve efficiencies of 3.26% for poly(3-hexylthiophene) (P3HT):[6,6]-phenyl-C 61 -butyric acid methyl ester (PCBM) and 7.37% for poly[[4,8- b i s [(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7):[6,6]-phenyl-C 71 -butyric acid methyl ester (PC 71 BM) devices compared with 2.58% and 6.67% for the control devices respectively. The origin of the improvement is studied by investigating the influence of the transport barrier, morphology and recombination. Atomic force microscopy (AFM), photoluminescence (PL) and transient photocurrent (TPC) measurements prove the boosted performance originates from the improved f...

Zhongwei Wu, Tao Song, Zhouhui Xia, Huaixin Wei and Baoquan Sun

Click for full article