Tuesday, December 01, 2015

Increasing the Enhancement Factor in Plasmon-Enhanced Fluorescence with Shell-Isolated Nanoparticles

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.5b09215

S. A. Camacho, P. H. B. Aoki, P. Albella, Osvaldo N. Oliveira, C. J. L. Constantino and R. F. Aroca
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DFT Study of CO2 Activation on Doped and Ultrathin MgO Films.

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.5b10130

Sergio Tosoni, Davide Spinnato and Gianfranco Pacchioni
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Mobility of the 2-Methylimidazolate Linkers in ZIF-8 Probed by 2H NMR: Saloon Doors for the Guests

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The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.5b09312

Daniil I. Kolokolov, Alexander G. Stepanov and Hervé Jobic
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Flattened-Top Domical Water Drops Formed through Self-Organization of Hydrophobin Membranes: A Structural and Mechanistic Study Using Atomic Force Microscopy

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ACS Nano
DOI: 10.1021/acsnano.5b04049

Ryota Yamasaki, Yoshiyuki Takatsuji, Hitoshi Asakawa, Takeshi Fukuma and Tetsuya Haruyama
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Multistimuli-Regulated Photochemothermal Cancer Therapy Remotely Controlled via Fe5C2 Nanoparticles

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ACS Nano
DOI: 10.1021/acsnano.5b04706

Jing Yu, Yanmin Ju, Lingyun Zhao, Xin Chu, Wenlong Yang, Yonglu Tian, Fugeng Sheng, Jian Lin, Fei Liu, Yunhe Dong and Yanglong Hou
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Single-Molecule Tribology: Force Microscopy Manipulation of a Porphyrin Derivative on a Copper Surface

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ACS Nano
DOI: 10.1021/acsnano.5b05761

Rémy Pawlak, Wengen Ouyang, Alexander E. Filippov, Lena Kalikhman-Razvozov, Shigeki Kawai, Thilo Glatzel, Enrico Gnecco, Alexis Baratoff, Quanshui Zheng, Oded Hod, Michael Urbakh and Ernst Meyer
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Anti-MoS2 Nanostructures: Tl2S and Its Electrochemical and Electronic Properties

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ACS Nano
DOI: 10.1021/acsnano.5b05157

Xinyi Chia, Adriano Ambrosi, Zdeněk Sofer, Jan Luxa, David Sedmidubský and Martin Pumera
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Ultrasmall Cu3N Nanoparticles: Surfactant-Free Solution-Phase Synthesis, Nitridation Mechanism, and Application for Lithium Storage

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.5b03444

Rupali Deshmukh, Guobo Zeng, Elena Tervoort, Malwina Staniuk, David Wood and Markus Niederberger
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Study on the Intermixing of Core and Shell in NaEuF4/NaGdF4 Core/Shell Nanocrystals

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.5b03846

Simon Dühnen and Markus Haase
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Growth of Uniform Monolayer Graphene Using Iron-Group Metals via the Formation of an Antiperovskite Layer

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.5b02788

Linfeng Chen, Zhizhi Kong, Shuanglin Yue, Jinxin Liu, Jingwen Deng, Yao Xiao, Rafael G. Mendes, Mark H. Rümmeli, Lianmao Peng and Lei Fu
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Exciton Delocalization and Hot Hole Extraction in CdSe QD and CdSe/ZnS Type 1 Core Shell QD Sensitized with Newly Synthesized Thiols

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR07605F, Feature Article
HIRENDRA NATH GHOSH, Pallavi Singhal, Ganapati Subray Shankarling, Prashant V Ghorpade, Nancy Singhal, Sanjay kumar Jha, Raj Mangal Tripathi
The present work describes ultrafast thermalized and hot hole transfer processes from photo-excited CdSe quantum dot (QD) and CdSe/ZnS core-shell QD (CSQD) to newly synthesized thiols. Three thiols namely 2-Mercapto-N-phenylacetamide...
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Controllable In-situ Synthesis of Epsilon Manganese Dioxide Hollow Structure/RGO Nanocomposite for High-performance Supercapacitors

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR07900D, Communication
Mei Lin, Bolei Chen, Xiao Wu, Jiasheng Qian, Linfeng Fei, Wei Lu, WLH Chan, jikang Yuan
Well-organized epsilon-MnO2 hollow spheres/reduced graphene oxide (MnO2HS/RGO) composites have been successfully constructed via a facile and one-pot synthetic route. The [varepsilon]-MnO2 hollow spheres with the diameter of ~500 nm were...
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Direct synthesis of large-scale hierarchical MoS2 films nanostructured with orthogonally oriented vertically and horizontally aligned layers

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05938K, Paper
Xiaoyan Zhang, Saifeng Zhang, Bohua Chen, Hao Wang, Kan Wu, Yang Chen, Jintai Fan, Shen Qi, Xiaoli Cui, Long Zhang, Jun Wang
Hierarchical MoS2 nanofilms with orthogonally oriented vertical/horizontal layers are synthesized in an organic medium containing a small amount of water, and exhibit superior Q-switching behaviour in a fiber laser.
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Addressing asymmetry of the charge and strain in a two-dimensional fullerene peapod

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06271C, Communication
Vaclav Vales, Tim Verhagen, Jana Vejpravova, Otakar Frank, Martin Kalbac
A new two dimensional C70 fullerene peapod was prepared by a sequential assembly of 12 C graphene, C70 fullerenes and 12C graphene. The isotope labelling of graphene layers allowed us...
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Optical identification of layered MoS2 via characteristic matrix method

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06287J, Paper
Jun Wang, Yuanxin Li, Ningning Dong, Saifeng Zhang, Kangpeng Wang, Long Zhang
It is demonstrated that the characteristic matrix method is effective and reliable for the optical identification of two-dimensional layered nanomaterials on different substrates. By using this method, the authors calculate...
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Can antimonide-based nanowires form wurtzite crystal structure?

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR07362F, Paper
Sepideh Gorji Ghalamestani, Sebastian Lehmann, Kimbery Dick Thelander
The epitaxial growth of antimonide-based nanowires has become an attractive subject due to their interesting properties required for various applications such as long-wavelength IR detectors. The studies conducted on antimonide-based...
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Carbon quantum dots decorated Cu2S nanowire arrays for enhanced photoelectrochemical performance

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06908D, Paper
Ming Li, RenJie Zhao, Yanjie Su, Zhi Yang, Yafei Zhang
The photoelectrochemical (PEC) performance of Cu2S nanowire arrays (NWAs) has been demonstrated to be greatly enhanced by dipping-assembly of carbon quantum dots (CQDs) on the surfaces of Cu2S NWAs. Experimental...
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Nanogenerators Based on Vertically Aligned InN Nanowires

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06841J, Paper
Guocheng Liu, Songrui Zhao, Robert D. E. Henderson, Zoya Leonenko, Eihab Abdel-Rahman, Z. Mi, Dan B
Piezoelectric nanogenerators (NGs) based on vertically aligned InN nanowires (NWs) are fabricated, characterized, and evaluated. In these NGs, arrays of p-type and intrinsic InN NWs prepared by plasma-assisted molecular beam...
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Cross-stacked plasmonic nanowire network for high-contrast femtosecond optical switching

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06464C, Paper
Yuanhai Lin, Xinping Zhang, Xiaohui Fang, Shuyan Liang
We report an ultrafast optical switching device constructed by stacking two layers of gold nanowires into a perpendicularly crossed network,which works faster than 280 fs with an on/off modulation depth...
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Intracellular degradation of chemically functionalized carbon nanotubes using a long-term primary microglial culture model

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR06625E, Paper
Cyrill Bussy, Caroline Nedima Hadad, Maurizio Prato, Alberto Bianco, Kostas Kostarelos
Chemically functionalized carbon nanotubes (f-CNTs) have been used in proof-of-concept studies to alleviate debilitating neurological conditions. Previous in vivo observations in brain tissue have suggested that microglia - acting as...
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Targeted silver nanoparticles for ratiometric cellular phenotyping

Nanoscale, 2015, Accepted Manuscript
DOI: 10.1039/C5NR07928D, Communication
Anne-Mari Anton Willmore, Lorena Simon-Gracia, kadri toome, paarn paiste, venkata ramana kotamraju, tarmo molder, kazuki n sugahara, Erkki Ruoslahti , Gary B Braun, tambet teesalu
Affinity targeting is used to deliver nanoparticles to cells and tissues. For efficient targeting, it is critical to consider the expression and accessibility of the relevant receptors in the target...
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Predicting a new phase (T[prime or minute][prime or minute]) of two-dimensional transition metal di-chalcogenides and strain-controlled topological phase transition

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR07715J, Paper
Fengxian Ma, Guoping Gao, Yalong Jiao, Yuantong Gu, Ante Bilic, Haijun Zhang, Zhongfang Chen, Aijun Du
A new T[prime or minute][prime or minute] MoS2 phase and strain controlled topological phase transition are reported.
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Preparation of hollow microsphere@onion-like solid nanosphere MoS2 coated by a carbon shell as a stable anode for optimized lithium storage

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05595D, Paper
Bangjun Guo, Ke Yu, Haili Song, Honglin Li, Yinghua Tan, Hao Fu, Chao Li, Xiang Lei, Ziqiang Zhu
Hollow microsphere@solid nanosphere MoS2 was synthesized via a facile one-step hydrothermal process, then coated with carbon shell for use as an anode material with enhanced lithium storage performance.
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Tumor specific liposomes improve detection of pancreatic adenocarcinoma in vivo using optoacoustic tomography

Background: Pancreatic cancer often goes undiagnosed until late stage disease due in part to suboptimal early detection. Our goal was to develop a Syndecan-1 tagged liposome containing fluorescent dye as an improved contrast agent for detection of pancreatic adenocarcinoma in vivo using multispectral optoacoustic tomography. Results: The diagnostic capabilities and specificity to pancreatic adenocarcinoma of Syndecan-1 targeted liposomes were evaluated both in vitro and in vivo. Immunocytochemistry showed that liposomes preferentially bound to and released their contents into cells expressing high levels of insulin-like growth factor 1 receptor. We determined that the contents of the liposome were released into the cell as noted by the change in propidium iodide fluorescence from green to red based upon nucleic acid binding. In an orthotopic mouse model, the liposomes preferentially targeted the pancreatic tumor with little off-target binding in the liver and spleen. Peak accumulation of the liposomes in the tumor occurred at 8 h post-injection. Multispectral optoacoustic tomographic imaging was able to provide high-resolution 3D images of the tumor and liposome location. Ex vivo analysis showed that non-targeted liposomes accumulated in the liver, suggesting that specificity of the liposomes for pancreatic adenocarcinoma was due to the presence of the Syndecan-1 ligand. Conclusions: This study demonstrated that Syndecan-1 liposomes were able to release cargo into IGF1-R expressing tumor cells. The Syndecan-1 liposomes demonstrated tumor specificity in orthotopic pancreatic cancer as observed using multispectral optoacoustic tomography with reduced kidney and liver uptake. By targeting the liposome with Syndecan-1, this nanovehicle has potential as a targeted theranostic nanoparticle for both drug and contrast agent delivery to pancreatic tumors.
Wenyuan Yin
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Monday, November 30, 2015

Effect of the Ligand Structure on Chemical Vapor Deposition of WNxCy Thin Films from Tungsten Nitrido Complexes of the Type WN(NR2)3

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.5b03691

Arijit Koley, Christopher T. O’Donohue, Michelle M. Nolan, K. Randall McClain, Richard O. Bonsu, Roman Y. Korotkov, Tim Anderson and Lisa McElwee-White
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Metal Organic Frameworks Derived Hierarchical Hollow NiO/Ni/Graphene Composites for Lithium and Sodium Storage

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ACS Nano
DOI: 10.1021/acsnano.5b05041

Feng Zou, Yu-Ming Chen, Kewei Liu, Zitian Yu, Wenfeng Liang, Sarang M. Bhaway, Min Gao and Yu Zhu
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