Thursday, January 02, 2014

Solution self-assembly and phase transformations of form II crystals in nanoconfined poly(3-hexyl thiophene) based rod-coil block copolymers




Nanoscale , 2014, Advance Article

DOI: 10.1039/C3NR04214F, Paper

Yi-Huan Lee, Yi-Lung Yang, Wei-Che Yen, Wei-Fang Su, Chi-An Dai

During solution assembly, P3HT-P2VP first formed nanoseed aggregates followed by the directional growth of nanofibrils driven by the formation of prevailing form II crystals within nanoconfined fibril core surrounded by amorphous P2VP block.

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