Tuesday, November 03, 2015

Tailoring open metal sites for selective capture of CO2 in isostructural metalloporphyrin porous organic networks

Nanoscale, 2015, Advance Article
DOI: 10.1039/C5NR05696A, Communication
Hwa Seob Choi, Hyung Joon Jeon, Jung Hoon Choi, Gyu-Heon Lee, Jeung Ku Kang
CO2 can be selectively captured over N2 or Ar by tuning the metalloporphyrin building units of isostructural porous organic networks, giving a selectivity correlated with heat of adsorption via adsorbate-adsorbent interactions.
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