Facile nucleation of gold nanoparticles on graphene-based thin films from Au 144 molecular precursors

We demonstrate a facile and cost effective method to obtain gold nanoparticles on graphene by dispersing Au 144 molecular nanoclusters by spin coating them in thin layers on graphene-based films and subsequent annealing in a controlled atmosphere. The graphene-based thin films used for these experiments are prepared by solvent-assisted exfoliation of graphite in water in the presence of ribonucleic acid as a surfactant and by subsequent vacuum filtration of the resulting graphene-containing suspensions. Not only is this method easily reproducible, but it leads to gold nanoparticles that are not dependent in size on the number of graphene layers beneath them. This is a distinct advantage over other methods. Plasmonic effects have been detected in our gold nanoparticle-decorated graphene layers, indicating that these thin films may be useful in applications such as plasmonic solar cells and optical memory devices.

Andrei Venter, Mahdi Hesari, M Shafiq Ahmed, Reg Bauld, Mark S Workentin and Giovanni Fanchini

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