Role of anion polarizability in fluorescence sensitization of DNA-templated silver nanoclusters

Fluorescent silver nanoclusters (Ag NCs) as novel fluorophores have received much attention because of their high brightness, good photostability and widely tunable emissions from the visible to the near-infrared range as a result of their size and existing environment. However, efforts are still needed to find the factors that tune the emission of Ag NCs. In this work, Ag NCs that were size-selectively grown on DNA were used to investigate the effect of the electronic properties of coordinating ligands. Halogen anions were used as the paradigm because of their periodicity in element properties. We found that addition of halogen anions did not alter the emission wavelength of Ag NCs, but the fluorescence intensity showed an initial increase at low concentrations of Cl – , Br – and I – followed by a gradual decrease at high concentrations. No increase in fluorescence was observed for F – at either low or high concentration. Such specific halo...

Jian Peng, Yong Shao, Lingling Liu, Lihua Zhang, Wensheng Fu and Hua Liu

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