Thursday, May 15, 2014

Self-assembly of 21-arm star-like diblock copolymer in bulk and under cylindrical confinement




Nanoscale , 2014, Advance Article

DOI: 10.1039/C4NR01275E, Paper

Yuci Xu, Weihua Li, Feng Qiu, Zhiqun Lin

Phase behavior of 21-arm star-like diblock copolymer in bulk and under confinement was explored. A symmetrical phase diagram was constructed. The gyroid phase was found to possess a large phase region when the inner block has a small volume fraction. The bridging fraction of the lamellae phase was nearly 100%, which is advantageous for improving its mechanical property.

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