Monday, November 03, 2014

New insights into the early stages of silica-controlled barium carbonate crystallisation




Nanoscale , 2014, Advance Article

DOI: 10.1039/C4NR05436A, Paper

Josef Eiblmeier, Ulrich Schurmann, Lorenz Kienle, Denis Gebauer, Werner Kunz, Matthias Kellermeier

Additive-controlled mineralisation involves complex interactions at various length scales. Here, we study the nucleation of barium carbonate in the presence of silica by combining in situ potentiometric titrations and ex situ analyses of formed particles. The results highlight distinct effects at all stages and explain self-assembly phenomena in these systems.

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