Remarkable Enhancement in Ligand-Exchange Reactivity of Thiolate-Protected Au25 Nanocluster by Single Pd Atom Doping

Yuichi Negishi

Nanoscale , 2012, Accepted Manuscript

DOI: 10.1039/C2NR32948D, Communication

Yoshiki Niihori, Wataru Kurashige, Miku Matsuzaki, Yuichi Negishi

The effect of Pd doping on the ligand-exchange reactivity of Au25(SC12H25)18 was studied by comparing the ligand-exchange reactivity of [Au25(SC12H25)18]- and [PdAu24(SC12H25)18]0 and the results clearly demonstrate that, regardless of...

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