Structural and electrochemical studies of Sm@D3h-C74 reveal a weak metal-cage interaction and a small band gap species

Nanoscale , 2013, Accepted Manuscript

DOI: 10.1039/C3NR03447J, Paper

Wei Xu, Yajuan Hao, Filip Uhlik, Zujin Shi, Zdenek Slanina, Lai Feng

A metallofullerene Sm@D3h-C74 that contains a divalent rare-earth metal has been studied structurally and electrochemically. The crystallographic analysis revealed that the endohedral Sm atom is more or less motional rather...

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