Monday, August 12, 2013

Transition voltage spectroscopy reveals significant solvent effects on molecular transport and settles an important issue in bipyridine-based junctions




Nanoscale , 2013, Advance Article

DOI: 10.1039/C3NR51290H, Paper

Ioan Baldea

Results of a seminal study (B. Xu and N. J. Tao, Science, 2003, 301, 1221) on molecular junctions based on bipyridine placed in a solvent have been challenged recently (S. Y. Quek et al., Nat. Nano, 2009, 4, 230) by implicitly assuming a negligible solvent impact on the molecular transport and by merely considering low bias conductance data.

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